As you have decided to leave the current job, inform your boss in a polite way and ask him if there's anything he wants you to finish before you leave the job.

Give sufficient notice

If you have got sufficient time to join the new company, give notice to the HR department so that they can look out for your replacement and the work doesn't suffer.

Dont leave the things hanging

If there are things that need your presence to be accomplished, finish them. Don't leave the things hanging in the air. Your replacement would not know the background. And will not be able to take a fast action which can make the work suffer. If the work of other departments is linked to yours, inform them about your switching the job and co-operate with them to finish the pending things.

The bottom line is, don't let your job switch affect your personal relationship with the present company.

Resources on Career, CV, Cover Letter, Interview, Work From Home etc.

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Quitting the job

Quitting the job?-Leave on a good note

Inform your boss

Give sufficient notice

Dont leave the things hanging